Crystal structure of 2-(2-methylphenyl)-1,3-thiazolo[4,5-b]pyridine
نویسندگان
چکیده
In the title mol-ecule, C13H10N2S, the dihedral angle between the planes through the non-H atoms of the methylbenzene and thi-azo-lopyridine groups is 36.61 (5)°. In the crystal, the thi-azo-lopyridine groups of inversion-related mol-ecules overlap, with a minimum ring-centroid separation of 3.6721 (9) Å. Furthermore, the methylbenzene groups from neighbouring mol-ecules inter-act edge-to-face at an angle of 71.66 (5)°. In addition, weak C-H⋯ N hydrogen bonds form chains exending along [100].
منابع مشابه
Crystal structure of 2-(1-methylethyl)-1,3-thiazolo[4,5-b]pyridine
In the title mol-ecule, C9H10N2S, one of the methyl groups is almost co-planar with the thia-zolo-pyridine rings with a deviation of 0.311 (3) Å from the least-squares plane of the thia-zolo-pyridine group. In the crystal, weak C-H⋯N hydrogen-bonding inter-actions lead to the formation of chains along [011].
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In the title compound, C12H7N3O2S, the dihedral angle between the planes of the thia-zolo-pyridine ring system (r.m.s. deviation = 0.005 Å) and the benzene ring is 3.94 (6)°. The nitro group is rotated by 7.6 (2)° from its attached ring. In the crystal, extensive aromatic π-π stacking [shortest centroid-centroid separation = 3.5295 (9) Å] links the mol-ecules into (001) sheets.
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The title compound, C10H12N2S, does not contain any strong hydrogen-bond donors but two long C-H⋯N contacts are observed in the crystal structure, with the most linear inter-action linking mol-ecules along [010]. The ellipsoids of the tert-butyl group indicate large librational motion.
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In the title compound, C12H14N2S, the cyclo-hexane ring adopts a chair conformation with the exocyclic C-C bond in an equatorial orientation. The mean plane through the cyclo-hexane ring (all atoms) is twisted from the thia-zolo-pyridine ring system (r.m.s. deviation = 0.013 Å) by 39.57 (6)°. In the crystal, mol-ecules form (100) sheets, although there are no specific directional inter-actions ...
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In the title compound, C(19)H(15)FN(4)S(2), the mean plane of the thia-zolopyrimidine makes a dihedral angle of 77.6 (1)° with the attached phenyl ring. The crystal packing is stabilized by inter-molecular C-H⋯N hydrogen bonds and weak C-H-π stacking inter-actions.
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